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Yun et al. Soft Sci 2023;3:12  https://dx.doi.org/10.20517/ss.2023.04            Page 3 of 23

               mode and materials, elucidating comprehensive guidelines for practical cooling solutions in wearable
               devices and defining suitable heat dissipation modes across diverse wearable platforms. In Section
               “Thermal  management   structures   for  wearable  devices”,  the  essential  mechanisms  for  managing  the
               thermal conditions of the user, both  internally  and  externally,  are  introduced,  along  with  the  effective
               structures  for  thermal  management  in wearable devices. In five major sections, thermal management
               structures, multifunctional applications for flexible substrates and wearable devices, and active thermal
               management techniques for dynamically changing materials and radiative cooling structures are explored.
               The review concludes with a roadmap for the practical application and development of fully integrated
               multifunctional thermal management systems for wearable devices and highlights future directions and
               opportunities in thermal management for advanced wearable devices.


               THERMAL MANAGEMENT STRUCTURES FOR WEARABLE DEVICES
               Wearable devices are generally composed of sensors, electrodes, and flexible substrates, which are combined
               with integrated circuits and other parts to enable real-time monitoring of biosignals in daily life. The devices
               typically  include  a  variety  of  sensors.  Sensors  for  electrocardiograms  (ECGs) [1,51-56] , EMG [57-60] , and
               photoplethysmography (PPG) [61-65]  are used to monitor heart rate, body motions, and pulse oximeters,
               respectively. Temperature and humidity are measured by resistance sensors [66-73] , while Galvanic skin
               response sensors have become popular tools for stress monitoring because of their ability to utilize
               sweat [74-77] . Sweat sensors detect glucose levels through an electrochemical process in sweat transported
               through microfluidic channels [78-84] .

               Thermal management through heat transfer mode
               Figure 1 shows an overview of thermal control considerations for wearable devices. Generally, different
               pathways of heat dissipation contribute to wearable device thermal management: conduction, radiation,
               convection/evaporation, heat absorption/release, and thermoelectric (TE) cooling. The transfer of heat
               resulting from the temperature difference between two physically contacting objects is known as thermal
                         [85]
               conduction . According to Fourier’s law, the rate of heat transmission across a medium increases as the
                                  [86]
               temperature decreases .






               where q denotes the heat flux, λ is the thermal conductivity coefficient and ∂T/∂x is the temperature
               gradient. Heat transmission in the steady state is primarily defined by effective thermal conductivity. Most
               heat created by wearable devices is transmitted to the skin or, when fitted with a heat sink, to the ambient
                 [87]
               air . Efficient heat dissipation is critical to prevent heat transfer to the skin, which can be achieved by
               either attaching a flexible heat sink to the device or introducing nanofillers with high thermal conductivity
               embedded in the substrate material .
                                             [88]

                                                                                                    [89]
               Radiation is an electromagnetic wave emitted by an object with a temperature above absolute zero . The
               energy dissipation rate depends on the temperature differential between the object and its immediate
               surroundings, the surface emissivity, and the effective surface area. Thus, surface absolute temperature is the
               main factor used to determine total radiant heat power through the Stefan-Boltzmann law .
                                                                                          [90]
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