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Zheng et al. Soft Sci. 2026, 6, 32                                               Page 23 of 57





               Table 2. Key performance indicators and application features of MXene and graphene fibres are compared
               Performance       GF                MXene fiber                Remarks           Ref.
               dimension
                                                                              GF superior; MXene
                                                   ≤ 585.5 (pure); ≤ 1,060.1 (composite); ≤
               Tensile strength (MPa)  ≤ 5,190                                composite breaks 1 GPa  [19,35,119,120]
                                                   1,037.9 (natural fiber composite)
                                                                              barrier
                                                                              GF much stiffer; MXene
                                 ≤ 901 (composite); ≤ 400
               Young’s modulus (GPa)               ≤ 29.6 (pure); ~0.33 TPa (monolayer)  monolayer ultra-high  [17,50,114,117]
                                 (pure)
                                                                              modulus
                                                                              MXene composites show
               Toughness (MJ·m )  ≤ 24.0           ≤ 194.9                                      [61,120]
                          -3
                                                                              record toughness
                                                                              Graphene has higher upper
               Electrical conductivity  ≤ 1.2 × 10 6  ≤ 12,503 (pure); ≤ 7,748 (LC spinning);  limit; MXene reaches 10 4  [18,33,34,122]
                                                          4
                   -1
               (S·cm )                             ≤ 1.27 × 10  (composite)
                                                                              level
                                                                              Graphene excels in heat
               Thermal conductivity  ≤ 1,435       Low (limited macro-fiber data; mainly  conduction; MXene favors  [14]
                   -1
                     -1
               (W·m ·K )                           photothermal effect)
                                                                              photothermal conversion
                                                                              MXene denser, less
                        -3
               Density (g·cm )   ~1.4-1.9          ~2.0-3.0 (pure); ~3.6 (chitosan bath)        [15,21-24,26]
                                                                              lightweight
                                                                              Graphene more mature in
               Specific surface area  ≤ 2,605 (2,210 after  Moderate (> 96.5% porosity aerogel  porous/high-SSA design;
               (m ·g )           reduction)        fiber)                     MXene aerogel fibers  [28,77]
                 2
                   -1
                                                                              emerging
                                 Good (stable carbon  Excellent (atomic-layer deformability,
               Intrinsic         structure, but elongation < ​  large strain possible, > 34% fracture  MXene excels in out-plane  [35]
               flexibility/bendability                                        flexibility and stretchability
                                 5%)               strain)
                                 Excellent                                    Graphene far more stable;
               Environmental stability  (oxidation-resistant,  Poor (prone to oxidation in humid air;  MXene requires protection  [131]
                                 hygrothermal stable)  requires encapsulation/compositing)  strategies
                                                   Excellent (no reduction needed,
                                 Good (requires GO  abundant hydrophilic groups, direct  MXene easier to process,
               Solution processability                                        compatible with various wet [136]
                                 dispersion + reduction)  aqueous processing, up to 19.4 wt%
                                                   colloidal ink)             methods
                                 High strength and
                                 conductivity, thermal  High capacitance (1,265 F·cm ),  Overlap in shielding but
                                                                      -3
               Key application   management, structural  photothermal conversion, tunable  different mechanisms;
               advantages        reinforcement, EMI  surface chemistry, EMI shielding,  MXene excels in  [33]
                                 shielding, fiber-shaped  self-healing, TENGs  electrochemical energy
                                 batteries                                    storage
                                 Low elongation at break (< ​
                                 5%), defect control in  Moderate strength/modulus of pure
               Main performance  large-scale spinning,  fiber, insufficient long-term stability,  Need scenario-specific  [119]
               bottlenecks                         oxidation sensitivity, immature  optimization
                                 high-temperature reduction
                                 energy cost       antioxidant strategies
                                 Structural health
                                 monitoring,       Flexible supercapacitors, strain sensors  Graphene:
                                 high-performance wires,  (GF up to 2,269.3), IR stealth,  structure-function
               Typical application  thermal interface materials,  electrothermal therapy, self-healing  integration; MXene: high  [120]
               scenarios                                                      electrochemical activity +
                                 fiber-shaped batteries, IR  textiles, TENGs, smart thermal
                                 thermotherapy fabrics, EMI  management fabrics  flexibility + multimodal
                                 shielding fabrics                            sensing
               All performance data are representative optimal values reported in the literature cited within the main text. GF: Graphene fiber; LC: SSA: GO:
               graphene oxide; EMI: electromagnetic interference; TENGs: triboelectric nanogenerators; IR: infrared.
               and electrical conductivity, are provided by the electronic arrangement of transition metal elements in
               MXene. These characteristics are heavily impacted by synthesis conditions including etchant type and
               exfoliation procedure in addition to the structure and makeup of the precursor MAX phase. More
               significantly, the elemental composition of M and X sites and surface functional groups (such as -OH, -F,
               and -O) can be dynamically controlled to further personalize MXene characteristics, allowing for broad
               adaptability to a variety of application needs. Several important features of MXene in conductive fibers are
               methodically explained in the sections that follow . Before going into the specific characteristics of MXene
                                                         [112]
               fibers, Table 2 compares them directly to GFs to show their existing limits and complimentary advantages.
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