Page 69 - Read Online
P. 69

Page 6 of 25                              Lin et al. Soft Sci 2023;3:14  https://dx.doi.org/10.20517/ss.2023.05


                                                                                                         ©
                structure of the device. Right frames: optical micrography of the e-skin compass. Reproduced with permission from Ref. [41] . Copyright
                2018. Springer Nature; (F) An active matrix consisting of micro-origami sensor arrays. Left frame: structure of the device. Inset of the
                left frame shows the micrograph of the AMR sensors. Right frame: optical image of an integrated micro-origami magnetic sensor device
                                                                                              ©
                with 8 × 8 pixels. Right frame: magnified view of several pixels. Reproduced with permission from  Ref. [87] . Copyright  2022. Springer
                Nature; (G) Schematic illustration of the structure and mechanism of a TMR sensor; (H) A flexible TMR sensor. Top frames:
                transmission electron microscopy (TEM) images of the MTJ structure. Bottom frame: optical image of MTJs transferred onto nitrile
                                                          ©
                glove. Reproduced with permission from  Ref. [104] . Copyright  2016. John Wiley and Sons; (I) A film-type strain gauge with the
                exchange-biased MTJ. Left frame: schematic illustration of the device. Top right frame: optical image of the motor-driven tensile
                                                                                                 ©
                machine for the sample. Bottom right frame: illustration of structure. Reproduced with permission from Ref. [107] . Copyright  2022. AIP
                Publishing. AFM: Antiferromagnetic; AMR: anisotropic magnetoresistance; GMR: giant magnetoresistance; MTJs: magnetic tunneling
                junctions; PET: polyethylene terephthalate; SCMN: stretchable and conformable matrix network; TMR: tunneling magnetoresistance.
               One important direction of soft GMR sensors focuses on investigating the influence of different flexible
               substrates on the performance of the GMR device, in order to develop magnetic sensors with desired
               sensitivity, flexibility and mechanical endurance for applications in biomedicine or other bio-integrated
               systems [75,76] . Figure 2B introduces electronic skins (e-skins) integrated with GMR sensors. Such e-skins
               allow wearers to perceive the presence of static or dynamic magnetic field, thereby expanding the sensing
               capability of the human body. Here, the highly sensitive GMR sensor elements are on an ultrathin
               (thickness: 1.4 μm) polyethylene terephthalate (PET) foil with mechanical properties of light weight and
                                                                               -1
               high strength. The GMR sensors exhibit high sensitivities of up to 0.25% Oe , identical to their counterparts
               on rigid Si/SiO  wafer substrates. The e-skins are thin enough to provide an imperceptible feature during
                            2
                                                                                     [77]
               wearing and can withstand cyclic tensile strains (270%, 1000 cycles) without fatigue .
               The incorporation of photolithographic techniques into these magnetoelectronic nanomembranes on
               ultrathin plastic foils enables the fabrication of devices with accurate patterns over large areas and in a
               multiplexed array format. These resulting sensor arrays exhibit flexibility, stretchability, and mechanical
               robustness and can integrate with other soft electronics to form a multifunctional system. Figure 2C shows a
               skin-inspired, highly stretchable and conformable matrix network (SCMN) that combines multiple
               functions, including but not limited to the sensing capabilities of temperature, in-plane strain, humidity,
               light intensity, magnetic field, pressure, and proximity . The multilayer design [left frame of Figure 2C]
                                                              [78]
               separates six different types of sensor units in different layers to avoid complicated wiring. The magnetic
               field sensors exploit multilayers of Co/Cu as the GMR elements (MR ratios: 50%), and locate in the middle
               of the multilayer stacks. The combination of magnetic field sensors with other devices allows for
               simultaneous measurements of various signals induced by the external environment, providing immediate
               applications in navigation, touchless control, and human-machine interface.


               Other examples of soft electronics based on GMR nanomembranes include printable GMR sensors for low-
               cost large-area production and easy integration with wearable devices and textiles [79,80] , highly integrated
               magneto-sensitive  electronic  membranes  for  extensive  applications  in  the  field  of  interactive
                                                                                              [83]
               electronics [81,82] , GMR 3D angular encoders with high angular accuracy in all directions , and many
               more [84-86] .

               Soft electronics based on AMR effect
               Compared with GMR nanomembranes, whose resistance only depends on the intensity of the magnetic
               field, the resistance change of AMR sensors depends on both the intensity and the direction of the magnetic
               field. The AMR effect is an important physical phenomenon in spintronics, where the angle between the
               current flow and magnetization direction determines the resistance of the ferromagnetic material
               [Figure 2D]. Compared with GMR sensors, AMR sensors usually have a smaller resistance change under a
               magnetic field. However, the capability to distinguish the direction of magnetic field underpins unique
   64   65   66   67   68   69   70   71   72   73   74