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Rehman et al. Energy Mater 2024;4:400068  https://dx.doi.org/10.20517/energymater.2024.06   Page 35 of 64

               Table 2. Comparison of electrochemical performances of representative alloy-based anode materials for SIBs
                                                               Charge/        Current
                Anode materials Synthetic method         ICE   discharge   Cycles  density   Electrolyte  Ref.
                                                         [%]
                                                               capacity
                                                                                  -1
                                                                    -1
                                                              [mAh g ]       [mA g ]
                Tin-based anode materials
                Tin-based oxides
                SnO @CNFs/CNTs Electrospinning           54.3  460.3   200      100   NaClO /EC/PC/FEC  [76]
                  2
                                                                                          4
                SnO /C       Electrospinning             55.2  565     2,000    1,000  NaClO /EC/DEC  [77]
                  2-x                                                                     4
                SnO /NG      Hydrothermal                27.8  409.6   100      50    NaClO / PC/EC/FEC  [78]
                  2
                                                                                          4
                SnO /NiO@C   Electrospinning/deposition/carbonization  69.0  320  200  100  NaClO /EC/DEC/FEC  [205 ]
                  2                                                                       4
                SnO  NRs/GA  Hydrothermal                58.4  232     100      50    NaClO /EC/DEC   [79]
                  2
                                                                                          4
                SnO -hard carbon  Hydrothermal carbonization  36.6  184  250    0.1 C  NaClO /EC/PC   [80]
                  2                                                                       4
                a-SnO  NH    Oblique angle deposition    53.1  915     50       2,000   NaPF /EC/DMC/FEC  [81]
                    2
                                                                                         6
                SnO @hCNT    Hydrothermal                50.0  223     100      100   NaClO /EC/DEC   [82]
                  2                                                                       4
                SnO @CC      Solvothermal                85    498     100      200   NaClO /EC/DMC   [83]
                                                                                          4
                  2
                SnO /MXene   Hydrothermal                36.54  208.6  100      400   NaClO /EC/DEC   [84]
                  2                                                                       4
                BTO@SnO2@P-C  Template assisted solvothermal synthesis  -  144.4  10,000  10,000 NaClO /EC/DEC/FEC  [206 ]
                                                                                          4
                Tin-based sulfides
                SnS /Co S    Co-precipitation and hydrothermal  59.16  1,141.8  50  100  NaClO /DEC/ EC/FEC [85]
                  2  3 4                                                                  4
                SnO @SnS @NG  Hydrothermal               54.6  100     200      3,000  NaClO /EC/DEC  [92]
                      2
                  2
                                                                                          4
                SMS/C NBs    Wet chemical method         90.8  522.5   500      5,000  NaCF SO / DEGDME  [93]
                                                                                          3  3
                SnS /EPC     Nanocasting                 68    340     450      2,000  NaPF /DME      [86]
                  2
                                                                                         6
                SnS  QDs/Ti C  Hydrothermal              55.1  345.3   600      100   NaClO /EC/DEC/DMC [87]
                  2     3 2                                                               4
                SnS /FeS /rGO  Hydrothermal              65    768.3   100      100   NaClO /EC/DEC/FEC  [207 ]
                                                                                          4
                     2
                  2
                PEG-SnS /rGO  Hydrothermal               74.2  770     100      100   NaPF /EC/DEC    [88]
                     2                                                                   6
                1T-SnS /RGO  CVD/spray coating           97.4  648.1   100      500   NaClO /EC/ DMC  [89]
                                                                                          4
                    2
                SnS-SnS @GO  Solvothermal                69.7  450.6   100      100   NaClO /EC/DMC/   [90]
                     2                                                                    4
                                                                                      MEC/FEC
                ZnS/SnS @NCNFs Electrostatic spinning    -     174.5   1,000    5,000  NaClO /PC/EC/FEC  [91]
                     2                                                                    4
                Tin-based selenides
                SnSe @C      Solvothermal                83.1  182.7   1,000    5,000  NaCF SO /DIGLYME  [94]
                   2                                                                      3  3
                SnSe /ZnSe@PDA  Mechanical mixing        71.6  616     1,000    1,000  NaPF /DME      [96]
                                                                                         6
                   2
                SnSe  /Ti C T  Liquid phase reduction and selenylation  -  245  445  1,000  NaPF /DOL/DIGLYME [97]
                   2  3 2 x                                                              6
                MoSe /SnSe @C  hydrothermal reaction     63.7  591.4   110      100   NaClO /EC/PC/FEC  [98]
                                                                                          4
                        2
                   2
                Tin-based phosphide
                Sn P -GA     Hydrothermal-phosphidation   67.3  657    100      100   NaClO / EC/DMC  [102 ]
                 4 3
                                                                                          4
                Sn P @C      Solvothermal-phosphidation  64    420     300      200   NaClO / EC/DMC/FEC [103 ]
                 4 3
                                                                                          4
                Micron-sized Sn P  High energy mechanical milling  89.8  719.7  100  100  M NaPF  in diglyme   [104]
                          4 3
                                                                                           6
                                                                                      (DGM)
                Sn P @CNT/C  Hydrothermal reaction       85.2  742     150      200   NaPF /DME       [105]
                 4 3
                                                                                         6
                Sn P /RGO    Reduction/phosphorization   54.57  421.8  100      500   -               [101]
                 x y
                Sn P  HS@MXene  Phosphorization          82.3  373.2   150      100   NaPF / DEC/ EC/ FEC  [106]
                 4 3
                                                                                         6
                Sn/Sn P @MXene  Solvothermal             65.7  127.8   1,000    2,000  NaPF / DEC/ EC/ FEC  [107]
                   4 3
                                                                                         6
                Sn P /NG     Carbonization-phosphorization  52.6  203.1  300    1,000  NaClO / EC/DEC/FEC [99]
                                                                                          4
                 x y
   99   100   101   102   103   104   105   106   107   108   109