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Xie et al. Energy Mater. 2025, 5, 500127  https://dx.doi.org/10.20517/energymater.2025.48  Page 5 of 15



































                                         Figure 1. The schematic diagram of experimental process.







































                Figure 2. (A) X-ray diffraction (XRD) patterns of Bi Sb Te  powders synthesized under varying ball milling durations, with and
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                                                          3
                                                    0.5
                without post-synthesis annealing, illustrating the influence of mechanical processing and thermal treatment on phase composition. (B)
                XRD patterns of polycrystalline Bi Sb Te  bulks obtained from melt-spun ribbons, highlighting the structural differences between
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                                          1.5
                samples processed with and without the melt-spinning technique.
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