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Page 28 of 37 Ye et al. J Mater Inf 2023;3:15 https://dx.doi.org/10.20517/jmi.2023.08
Figure 22. The calculated enthalpy of mixing of liquid Fe-Y alloys at 1,873 K with the experimental data [121] and the calculations [127,131-133] .
Figure 23. Calculated partial enthalpy of (A) Fe and (B) Y in liquid Fe-Y alloys at 1,873 K with the experimental data [121,122] and the
calculations [127,131-133] .
SUMMARY
Three Fe-Er, Fe-Lu, and Fe-Y binary systems were reassessed through the CALPHAD method in the
present work according to the reliable experimental results and the earlier calculations in the literature. An
improvement to our previous assessments of the Fe-Tb and Fe-Dy binary systems was obtained by revising
the expressions of the Gibbs energies of Fe Tb and Fe Dy and thus eliminating the artificial break in their
2
2
heat capacity curves that appears in the earlier assessments. A set of available thermodynamic parameters