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Tao et al. Energy Mater 2022;2:200036 https://dx.doi.org/10.20517/energymater.2022.46 Page 19 of 35

milling method
S-carbon replica/ Li Ge P S Li Ge P S Combined mechanical and 1500 after 50 [148]
10.05 1.05 1.95 12 10.05 1.05 1.95 12
liquid-phase mixing cycles
Li S-TiS -electrolyte Electrolyte Two-step dry/wet-mixing 400 after 200 [103]
2 2
cycles

Figure 10. Cross-sectional SEM images exhibiting (A) the interface between a SSE and composites of Li S, AB and SE glass (reproduced
2
[115] [116]
with permission from ). (B) S-C-Li P Mn S I composite (reproduced with permission from ). (C) Cathode layer after cycling
7 2.9 0.1 10.7 0.3
(reproduced with permission from [117] ). (D) Bilayer framework with a clear PEO/LLTO solid composite electrolyte layer (thickness of 15
± 5 μm) (reproduced with permission from [118] ). (E) High-resolution TEM image of Li S-Li PS Cl-C sample and (F) cross-sectional SEM
6
2
5
images of interlayer-modified Li S pellet (reproduced with permission from [119] ).
2
reaction was used to fabricate graphene oxide/polyethylene glycol@C/S composite cathodes, which showed
a long cycling life (capacity retention of 86.6%) after 100 cycles . The introduction of graphene oxide and
[145]
polyethylene glycol is beneficial for increasing the electronic conduction and Li-ion diffusion pathway in the
cathode separately. A composite cathode of sulfur/AB/Li Ge P S was obtained by a high-temperature
3.25
0.25 0.75 4
ball milling (443 K) method, which contributed to the generation of the reaction between S and the
[146]
electrolyte and the formation of novel structural units .
Sulfur can be introduced into the mesopores of carbon replica by a combination method of gas-phase
mixing and ball milling for preparing a carbon replica-S and Li Ge P S composite electrode . The
[147]
0.25 0.75 4
3.25
employed carbon replica provides a good conductive framework for the composite cathode and the