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Page 18 of 35 Tao et al. Energy Mater 2022;2:200036 https://dx.doi.org/10.20517/energymater.2022.46

Table 3. Components, preparation method and electrochemical performance of composite cathodes
Performance
Composition of cathode materials Solid electrolyte Method -1 References
(mA hg )
S/Cu S/acetylene-black(AB)/ 80Li S·20P S Ball milling 650 after 20 cycles [120]
2 2 2 5
80Li S/20P S
2 5
2
S/poly(ethylene oxide)(PEO)/AB P(EO) Li(CF SO )2N-10 wt.% ϒ- Ball milling 290 after 50 cycles [121]
20 3 2
LiAlO 2
S/Carbon/PEO/acetonitrile (PEO) LiBF /Al O 3 Ball milling 400 after 10 cycles [122]
6
2
4
S/AB/thio-LISICON (Li Ge P S ) LISICON Ball milling 30 after 5 cycles [123]
3.25 0.25 0.75 4
Li S/Cu/80Li S/20P S 80Li S·20P S Ball milling 350 after 20 cycles [124]
2
2
2 5
2
2 5
80Li S/20P S /Cu 80Li S·20P S Ball milling 60 after 50 cycles [125]
2 2 5 2 2 5
S/AB/80Li S/20P S 80Li S·20P S Ball milling 850 after 200 [126]
2 5
2
2
2 5
cycles
Li S/A /80Li S/20P S 80Li S·20P S Ball milling 700 after 10 cycles [127]
2
2
2 5
2
2 5
S/graphite 80Li S·20P S Ball milling 400 after 20 cycles [128]
2 2 5
S/carbon/Thio-LISICON Thio-LISICON Ball milling 1000 after 50 [129]
cycles
Vapor-grown carbon fiber (VGCF)/S/ionic α-Li PS 4 Ball milling 1230 after 50 [130]
3
liquid/α-Li PS 4 cycles
3
S/activated carbon/P S Li GeP S Ball milling 1042 after 10 cycles [131]
2 5 10 2 12
S/super P carbon/Li PS Br Li PS Br Ball milling 1080 after 50 [132]
5
6
5
6
cycles
sulfur/AB/75Li S·25P S 75Li S·25P S Ball milling 450 after 20 cycles [115]
2
2 5
2
2 5
S-C/Li PS Cl/super P Li PS Cl Ball milling 400 after 20 cycles [133]
6 5 6 5
S/C/Li P Mn S I Li P Mn S I Ball milling 800 after 60 cycles [116]
0.1 10.7 0.3
7 2.9
7 2.9
0.1 10.7 0.3
S-graphene oxide/Li Si P S Cl Li Si P S Cl Ball milling 827 after 60 cycles [99]
9.54 1.74 1.44 11.7 0.3 9.54 1.74 1.44 11.7 0.3
/carbon black
Li S-VGCF/78Li S·22P S /Ketchen black 78Li S·22P S Ball milling 600 after 20 cycles [83]
2 5
2
2
2
2 5
conductive carbon
Reduced graphene oxide-S/Li GeP S /AB Li GeP S -75%Li S-24%P S Ball milling 830 after 750 [84]
10
2 12
2 12
10
2 5
2
-1%P cycles
O
2 5
S/AB/70Li S·30P S 70Li S·30P S Ball milling 673 after 5 cycles [134]
2 2 5 2 2 5
Li S/super P carbon/VGCF/70Li S·30P S 70Li S·30P S Ball milling 464 after 10 cycles [135]
2
2
2
2 5
2 5
S-C-FeS /Li PS -LiI Li PS -LiI Ball milling 800 after 20 cycles [136]
2 3 4 3 4
S-carbon nanotubes/multi-wall carbon 78Li S·22P S Ball milling 834.3 after 1000 [137]
2
2 5
nanotubes/78Li S·22P S cycles
2 2 5
S/3,5-divinylbenzene copolymer Lithium- Ball milling 800 after 50 cycles [138]
bis(fluorosulfonyl)imide/PEO
S-C/super P carbon/Li PS Br Li PS Br Ball milling 204 after 35 cycles [139]
6
5
6
5
S-carbon nanotubes/AB/Li GeP S Li GeP S /75%Li S-24%P S Ball milling 660.3 after 400 [45]
2
2 5
2 12
2 12
10
10
-1%P O cycles
2 5
Li PS 4+5 Li PS 4 Solution reaction 700 after 400 [140]
3
3
cycles
Li S-Li PS 4 β-Li PS 4 Solution reaction 402 after 100 [141]
3
2
3
cycles
S-Ketjen Black/ LiBH 4 LiBH 4 Cold-pressing 630 after 50 cycles [142]
Li S/C/Li PS Cl Li PS Cl Bottom-up approach 830 after 60 cycles [143]
2 6 5 6 5
S
S-carbon replica/ Li 3.25 Ge 0.25 0.75 4 Li 3.25 Ge 0.25 0.75 4 Gas-phase mixing and ball 500 after 10 cycles [129]
S
P
P
milling method
S- Li La Zr O -C Li La Zr O -PEO Pechini sol-gel method 700 after 200 [144]
3
2
12
2
3
7
12
7
cycles
Graphene oxide/polyethylene glycol @C/S PEO-a metal-organic framework- One-pot reaction 531 after 100 cycles [145]
LiTFSI
S/acetylene black/Li Ge P S Li Ge P S High-temperature 800 after 40 cycles [146]
3.25 0.25 0.75 4 3.25 0.25 0.75 4
mechanical milling
Carbon replica-S/Thio-LISICON Thio-LISICON Gas-phase mixing and ball 500 after 10 cycles [147]