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Page 4 of 34                                                 Wang et al. Energy Mater. 2026, 6, 600064
















































































               Figure 1. Additive-mediated regulatory mechanisms across the entire perovskite crystallization process. (A) Ordering colloidal distribution
               and stacking: Stacking configurations of perovskite colloids without (w/o) and with (w) fulleropyrrolidine. Reprinted with permission  [50] .
               Copyright 2025, John Wiley and Sons. (B) Tailoring intermediate phase selection: Structural evolution of FA-based perovskites under
               additive-free and TR-2-BA-modified conditions. Reprinted with permission [57] . Copyright 2025, John Wiley and Sons. (C) Controlling grain
               coarsening and nucleation: Crystallization pathways without (w/o) and with (w) PTCoPF 6 . Reprinted with permission [58] . Copyright 2024,
               John Wiley and Sons.
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