Page 80 - Read Online

Meng et al. J. Mater. Inf. 2025, 5, 3 https://dx.doi.org/10.20517/jmi.2024.74 Page 21 of 25

Copyright
© The Author(s) 2025.

REFERENCES
1. Abbet, S.; Sanchez, A.; Heiz, U.; et al. Acetylene cyclotrimerization on supported size-selected Pdn clusters (1 ≤ n ≤ 30): one atom is
enough! J. Am. Chem. Soc. 2000, 122, 3453-7. DOI
2. Li, Y.; Zhou, Z.; Yu, G.; Chen, W.; Chen, Z. CO catalytic oxidation on iron-embedded graphene: computational quest for low-cost
nanocatalysts. J. Phys. Chem. C. 2010, 114, 6250-4. DOI
3. Lee, D. H.; Lee, W. J.; Lee, W. J.; Kim, S. O.; Kim, Y. H. Theory, synthesis, and oxygen reduction catalysis of Fe-porphyrin-like
carbon nanotube. Phys. Rev. Lett. 2011, 106, 175502. DOI PubMed
4. Qiao, B.; Wang, A.; Yang, X.; et al. Single-atom catalysis of CO oxidation using Pt /FeO . Nat. Chem. 2011, 3, 634-41. DOI
x
1
5. Yang, X. F.; Wang, A.; Qiao, B.; Li, J.; Liu, J.; Zhang, T. Single-atom catalysts: a new frontier in heterogeneous. Acc. Chem. Res.
2013, 46, 1740-8. DOI PubMed
6. Akri, M.; Zhao, S.; Li, X.; et al. Atomically dispersed nickel as coke-resistant active sites for methane dry reforming. Nat. Commun.
2019, 10, 5181. DOI PubMed PMC
7. Han, B.; Guo, Y.; Huang, Y.; et al. Strong metal-support interactions between Pt single atoms and TiO . Angew. Chem. Int. Ed. Engl.
2
2020, 59, 11824-9. DOI
8. Jeong, H.; Lee, G.; Kim, B. S.; Bae, J.; Han, J. W.; Lee, H. Fully dispersed Rh ensemble catalyst to enhance low-temperature activity.
J. Am. Chem. Soc. 2018, 140, 9558-65. DOI
9. Wang, Y.; Arandiyan, H.; Scott, J.; Aguey-Zinsou, K.; Amal, R. Single atom and nanoclustered Pt catalysts for selective CO
2
reduction. ACS. Appl. Energy. Mater. 2018, 1, 6781-9. DOI
10. Bai, S.; Liu, F.; Huang, B.; et al. High-efficiency direct methane conversion to oxygenates on a cerium dioxide nanowires supported
rhodium single-atom catalyst. Nat. Commun. 2020, 11, 954. DOI PubMed PMC
11. Sun, C. N.; Wang, Z. L.; Lang, X. Y.; Wen, Z.; Jiang, Q. Synergistic effect of active sites of double-atom catalysts for nitrogen
reduction reaction. ChemSusChem 2021, 14, 4593-600. DOI
12. Wang, P.; Chang, F.; Gao, W.; et al. Breaking scaling relations to achieve low-temperature ammonia synthesis through LiH-mediated
nitrogen transfer and hydrogenation. Nat. Chem. 2017, 9, 64-70. DOI
13. Guo, X.; Gu, J.; Lin, S.; Zhang, S.; Chen, Z.; Huang, S. Tackling the activity and selectivity challenges of electrocatalysts toward the
nitrogen reduction reaction via atomically dispersed biatom catalysts. J. Am. Chem. Soc. 2020, 142, 5709-21. DOI
14. Ouyang, Y.; Shi, L.; Bai, X.; Li, Q.; Wang, J. Breaking scaling relations for efficient CO electrochemical reduction through dual-
2
atom catalysts. Chem. Sci. 2020, 11, 1807-13. DOI PubMed PMC
15. Chen, Z.; Chen, L. X.; Yang, C. C.; Jiang, Q. Atomic (single, double, and triple atoms) catalysis: frontiers, opportunities, and
challenges. J. Mater. Chem. A. 2019, 7, 3492-515. DOI
16. Galloway, J. N.; Townsend, A. R.; Erisman, J. W.; et al. Transformation of the nitrogen cycle: recent trends, questions, and potential
solutions. Science 2008, 320, 889-92. DOI
17. Foster, S.; Bakovic, S. I. P.; Duda, R. D.; et al. Catalysts for nitrogen reduction to ammonia. Nat. Catal. 2018, 1, 490-500. DOI
18. Fu, X.; Zhang, J.; Kang, Y. Recent advances and challenges of electrochemical ammonia synthesis. Chem. Catal. 2022, 2, 2590-613.
DOI
19. Iqbal, M. S.; Yao, Z.; Ruan, Y.; et al. Single-atom catalysts for electrochemical N reduction to NH . Rare. Met. 2023, 42, 1075-97.
2 3
DOI
20. Shang, H.; Liu, D. Atomic design of carbon-based dual-metal site catalysts for energy applications. Nano. Res. 2023, 16, 6477-506.
DOI
21. He, T.; Puente-Santiago, A. R.; Xia, S.; Ahsan, M. A.; Xu, G.; Luque, R. Experimental and theoretical advances on single atom and
atomic cluster-decorated low-dimensional platforms towards superior electrocatalysts. Adv. Energy. Mater. 2022, 12, 2200493. DOI
22. Chen, J.; Cao, H.; Chen, J.; et al. Heterogeneous two-atom single-cluster catalysts for the nitrogen electroreduction reaction. J. Phys.
Chem. C. 2021, 125, 19821-30. DOI
23. Yan, Z.; Ji, M.; Xia, J.; Zhu, H. Recent advanced materials for electrochemical and photoelectrochemical synthesis of ammonia from
dinitrogen: one step closer to a sustainable energy future. Adv. Energy. Mater. 2020, 10, 1902020. DOI
24. Qu, J.; Xiao, J.; Chen, H.; Liu, X.; Wang, T.; Zhang, Q. Orbital symmetry matching: achieving superior nitrogen reduction reaction
over single-atom catalysts anchored on Mxene substrates. Chinese. J. Catal. 2021, 42, 288-96. DOI
25. Wang, T.; Abild-Pedersen, F. Achieving industrial ammonia synthesis rates at near-ambient conditions through modified scaling
relations on a confined dual site. Proc. Natl. Acad. Sci. U. S. A. 2021, 118, e2106527118. DOI
26. Yao, Y.; Zhu, S.; Wang, H.; Li, H.; Shao, M. A spectroscopic study of electrochemical nitrogen and nitrate reduction on rhodium
surfaces. Angew. Chem. Int. Ed. Engl. 2020, 59, 10479-83. DOI
27. Ling, C.; Zhang, Y.; Li, Q.; Bai, X.; Shi, L.; Wang, J. New mechanism for N reduction: the essential role of surface hydrogenation.
2
J. Am. Chem. Soc. 2019, 141, 18264-70. DOI
28. Abghoui, Y.; Skúlason, E. Onset potentials for different reaction mechanisms of nitrogen activation to ammonia on transition metal
nitride electro-catalysts. Catal. Today. 2017, 286, 69-77. DOI