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Sun et al. Chem Synth 2023;3:16 https://dx.doi.org/10.20517/cs.2022.45 Page 7 of 17
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Figure 3. The enhancement of photothermal conversion efficiency by host-guest interaction between (A) CB[8] and MPT (reproduced
with permission from ref. [53] , Copyright 2019, John Wiley & Sons); (B) WP5 and TANI (reproduced with permission from ref. [54] ,
Copyright 2021, Elsevier B.V.).
complex actuated assembly can induce the extension of -conjugation in a supramolecular way, which leads
to the redshift of absorption spectrum and, therefore, enhanced photothermal conversion efficiency in NIR
biowindow. For nanomaterials, their photothermal conversion efficiency is closely related to size or
supramolecular arrangement. Therefore, through the host-guest interaction-induced size or supramolecular
arrangement, their photothermal performance can be flexibly manipulated.
HOST-GUEST INTERACTION-ACTUATED DEEP TUMOR PENETRATION OF