Page 141 - Read Online

Feng et al. Chem Synth 2023;3:37 https://dx.doi.org/10.20517/cs.2023.26 Page 7 of 16

Figure 4. A single micelles assembly method to 2D monolayered meso-hetero. (A) Preparation procedures of the 2D meso-hero
structure; (B) Structure models of the obtained 2D meso-hetero. This figure is quoted with permission from Lan et al. [52] . 2D: Two-
dimensional.

Figure 5. Schematic illustration of the synthetic procedure for vertically aligned mesoporous carbon thin films with well-ordered
[53]
mesostructures on various substrates at the centimeter scale. This figure is quoted with permission from Wang et al. .
the mesoporous carbon film prepared by this method has excellent high mesoporous properties, high
-1
2
specific surface areas (472 m ·g ), and pore sizes of up to 9.1 nm. This directional assembly process can be
highly regulated at the single micelle level, achieving precise thickness control of mesopores from
monolayers to multilayers and pore size control from 8.4 to 13.5 nm. Compared to traditional porous
carbon membrane sensors, carbon membranes with vertical mesoporous channels have high permeability,
-1
which shows a lower detection limit (50 nmol·L ) and higher DA detection sensitivity.
This single micelle assembly method provides a new method for multifunctional materials related to mass
transfer and diffusion and also plays a certain role in promoting the precise synthesis of mesoporous
materials . However, there is still a long way to go to achieve controllable preparation of crystalline
[54]
2DMMs.