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Sayed et al. Chem Synth 2023;3:20 https://dx.doi.org/10.20517/cs.2023.05 Page 3 of 6
Scheme 1. Pd/Lewis base cooperative catalysis for direct alkylation of acyclic esters with alkoxyallenes.
mediated asymmetric allylations and chiral Lewis base catalysis, allowing for the access of structurally
diverse products with high efficiency and excellent stereocontrol. It is anticipated that the concept of metal/
Lewis base cooperative catalysis will inspire more exciting discoveries in the future.
